
What is the structure of (C5H5)2Fe(CO)2? The pi-allyl ligand. 3-electron donor as neutral ligand, 4-electron donor as anionic.
Chapter 11 METALLOCENES AND SANDWICH COMPLEXES Metal-sandwich complexes occupy a major place i.
Metallocenes, a class of organometallic compounds featuring a transition metal sandwiched between two cyclopentadienyl (Cp) ligands, are pivotal in fields ranging from catalysis to materials science …
Due to the ferrocene name, the first found compound, this type of ferrocene-like structure is called metallocene. IUPAC describes a metallocene as a transition metal between two cyclopen-tadienyl …
research on metallocene catalysts has been highly visible in organometallic chemistry. A central piece of work in zirconocene catalyzed polymerizations of -olefins was the elucidation of ligand effects, the …
increasing need to understand clean metallocene solids to exploit their intrinsic physical properties. Here, we used high-quality metallocene single cry tals grown by the physical vapor transport (PVT) …
In this work, we present a protocol for representing the branching architecture of metallocene-catalyzed long chain branched polyethylene. We make use of Monte Carlo simulations to generate sets of …